Open in new window. Resize window. Right-click title bar, select "Always on Top".
App developers spend a lot of their time making up for the poor decisions of OS developers. A good window manager would give you tabs for free, PiP (aka an always-on-top window) for free, dark mode for free. Instead OS devs go overboard in simplifying things to the point that app devs have to pay the cost of delivering what users want.
Agreed. I use it all the time. There is an issue where the video in the pop-up can be slightly "laggy" for some reason, not sure why that is. Otherwise great feature.